From the Smiths, I very much like Hull University 15/3/1984. Hull University isn't a top quality bootleg, but there's a reasonable amount of very humourous chatter from Moz and the songs were performed brilliantly.
Some other favourites are -
Apollo Theatre, Oxford 15/3/1985
Versailles, France 1/12/1984
Hanley Victoria Hall, Stoke-on-Trent 16/3/1985
Hacienda, Manchester 4/2/1983
The last one there features the famous line while introducing Handsome Devil:
"I repeat, the only thing to be in 1983 is handsome. Handsome Devil!"
That will forever be one of the dorkiest and most hilarious lines that ever came out of his mouth on stage.